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Demeter Brownie by Demeter Cologne Spray 4 oz (Women) fragrance for men middle notes are cassis andA deeply rich and chocolatey pan of brownies is what you think of when you smell Brownie by Demeter. Using headspace technology, the scent for this fragrance was developed by analyzing the air around freshly baked brownies and identifying the fragrant molecules. These molecules are then reproduced to compose the fragrance.