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Palmitic acid, kahweol, and cafestol are key diterpene compounds in coffee that can activate Phase II detoxification enzymes in the liver, potentially increasing glutathione levels

3 It has been debated for many years whether oral glutathione supplementation translates into increased bioactive levels of glutathione in the body, since many believe that oral glutathione cannot be adequately absorbed and therefore, successfully utilized by the bodys cells

And we see great bioavailability both ways

Brandt LE, Bohn AA, Charles JB, Ehrhart EJ