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Thiolate conjugate bases are easily formed, and have proven to be excellent nucleophiles in S N 2 reactions of alkyl halides and tosylates

Recent reports by the group of Ball 138,139 have used rhodium-bound metallopeptides to catalyse modification of tryptophan by using a structure-directed approach

Miller R, Buehner G, Chang Y, Harper JM, Sigler R, Smith-Wheelock : Methionine deficient diet extends mouse lifespan, slows immune and lens aging, alters glucose, T4, IGF-1 and insulin levels and increases hepatocyte MIF levels and stress resistence