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Structural basis for the interaction between Golgi reassembly-stacking protein GRASP55 and Golgin45

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Because the initial step of HRP-catalyzed IBAL oxidation involves the generation of an IBAL resonant -hydroperoxyl/enolyl radical, which ultimately yields the 3-hydroxy-4,4-dimethyldioxetane intermediate the putative precursor of triplet acetone and formic acid 65 by thermolysis, O 2 ( 1 g ) may have arisen from the radical, according to the Russell mechanism 16